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This booklet offers a complete catalogue of easy information forms like units, maps, orders, timber and lists, written in Ada. Such information kinds are frequently utilized in structures programming. the most important concentration is on: - a uniform syntactic and semantic interface for all facts forms, - many implementation variations consistent with information style, all ac cessible via a unmarried interface, - a hierarchical procedure of the information varieties as a foundation for facts kind choice and implementation. assembly those pursuits is the most fulfillment of the ebook. the mix of effective applicability and simplicity of studying and upkeep is accomplished via the conscientiously elaborated interfaces of the catalogue's info varieties. those interfaces mix abstraction, that's precious for simple studying and for leaving implementation freedom, and sensible completeness, that's an important prerequisite for prime functionality in several program contexts. the choice of definitely the right information variety implementation for a given context is supported by means of the knowledge kind hierarchy which imposes assorted abstraction degrees, and an orthogonal scheme of implementation editions which are freely mixed. including the uniformity of interfaces, the hierarchical composition of results in a small code base, from which assorted implementation versions are generated utilizing a macro processor.
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In the near future we foresee the use of N M R active stable isotopes as an important research tool for oligosaccharides and their interactions with other molecules, in particular lectins. 37 Acknowledgment This work was supported by grants from the Swedish Research Council (VR), the Carl Trygger Foundation and the Swedish International Development Cooperation Agency (SIDA). References 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. ; Aebi, M. Science 2001, 291, 2364-2369.
Chem. Soc. 2002, 124, 9986-9987. 33. Sinton, S. ; Zax, D . B . ; Murdoch, J. B . ; Pines, A . Mol. Phys. 1984, 53, 333-362. 34. Emsley, J. ; Luckhurst, G . ; Stockley, C. P. Proc. R. Soc. Lond. A 1982, 381, 117-138. 35. ; Veracini, C. ; Shilstone, G . ; Zannoni, C. J. Chem. Phys. 1991, 94, 3928-3935. 36. Stevensson, B . ; Maliniak, A . J. Am. Chem. Soc. 2002, 124, 5946-5947. 37. Stevensson, B . ; Maliniak, A . J. Chem. Phys. 2003, 119, 2738-2746. 38. ; Widmalm, G . Magn. Reson. Chem. 1998, 36, 773-776.
Structure must therefore be described as a distribution of thermally accessible conformers sampled by glycosidic torsional motions. Anyone of these conformers can be important in protein interaction events. It is our goal here to present some new N M R based methodology for determination of these conformational distributions. Motion in carbohydrates has been considered previously using a number of approaches. The presence of motion can be qualitatively detected though inconsistencies in N O E data used to determine solution structures of carbohydrates (6).
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