By David P. Landau, Kurt Binder
I agree that it covers loads of themes, a lot of them are very important. they really comprise even more subject matters within the moment version than the 1st one. even though, the authors seldomly talk about one subject greater than a web page. it truly is like analyzing abstracts of papers. So when you already be aware of the stuff, you do not need this booklet. simply opt for a few papers (papers are no less than as much as date). if you happen to do not know whatever approximately Monte Carlo sampling, this e-book won't assist you an excessive amount of. So do not waste your funds in this e-book. Newman's e-book or Frenkel's booklet is far better.
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Additional info for A Guide to Monte Carlo Simulations in Statistical Physics, Second Edition
12]: “… The ﬁrst is related to the size of active species; due to the large size of anions the Coulombic attractions between cation and anion are relatively weak and the nature of anion does not affect signiﬁcantly the reactivity of cation. The second explanation is based on the assumed mechanism of the propagation step. 3 Kinetics of Ring-Opening Polymerization located on the CH2 groups. This is an additional argument that the counterion does not have to be removed far away from its position in the ground state to the transition state during the propagation step, and there is no reason for the activation energies for the propagation step on ions or ion-pairs to differ substantially.
In particular, for ionic polymerization a variety of physical forms of active center exists, including (free) ions, ion pairs (contact or separated), ion pair aggregates, covalent species and their aggregates, all of which are in equilibrium . 3). To the best of our knowledge, covalent–ionic species interconversions have been observed only in cationic polymerization [23, 24], whereas ion pair and covalent species aggregation is characteristic of anionic and coordination (pseudoanionic) processes, respectively [8b].
As the kinetics of ROP has been reviewed on several occasions in the past [3a, 4, 7, 12, 23, 24, 105–107], we will at this point present only a brief summary of the most important phenomena, complemented with some recent ﬁndings. The anionic polymerization of EO was, historically speaking, the ﬁrst ROP to conform to the living polymerization criteria. As early as the 1940s, Flory had observed that the anionic propagation of EO could proceed without side reactions, such as irreversible transfer and termination [108, 109].
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